As the industrialization of solid-state batteries accelerates, the limitations of traditional wet coating processes have become increasingly prominent, making them inadequate for manufacturing solid-state batteries with sulfide and oxide electrolytes. In contrast, dry electrode technology offers distinct advantages including solvent-free operation, high electrode density, superior structural stability, cost-effectiveness, and excellent material compatibility. It has become the core manufacturing solution for mass production of semi-solid and full solid-state batteries and is currently a key technological focus for leading battery manufacturers. Based on the material characteristics, practical application challenges, and commercialization requirements of solid-state batteries, dry electrode technology is replacing traditional wet processes as the mainstream manufacturing method for five irreplaceable technical and industrial reasons.
Sulfide and oxide solid electrolytes are chemically sensitive and structurally unstable. When manufactured using traditional wet processes, organic solvents such as NMP and residual moisture will trigger chemical reactions with solid electrolytes. These reactions damage the microstructure of electrolytes, degrade active materials, and generate harmful byproducts and gases, ultimately reducing cycle life and compromising safety. This has long been the fundamental bottleneck preventing wet processes from being applied to solid-state battery production.
Dry electrode technology adopts a fully solvent-free manufacturing approach, completing electrode preparation through dry powder mixing, mechanical film formation, and thermal compression. It completely avoids solvent corrosion and hydrolysis deterioration, achieving perfect compatibility with all types of solid electrolyte materials. Additionally, dry processing fully preserves the original conductive network of solid electrolytes and ensures efficient ion transmission. Currently, it is the most mature and scalable manufacturing technology for sulfide-based solid-state batteries.
Traditional wet manufacturing involves coating, high-temperature drying, and solvent evaporation. These processes commonly cause material shrinkage, binder migration, and micropore collapse, resulting in disordered internal pore structures and loose electrode stacking. This severely limits compaction density improvement and restricts the maximum energy density of solid-state batteries. Furthermore, wet processes struggle to produce high-loading thick electrodes, further constraining the capacity upgrade of single cells.
Dry electrode technology eliminates structural defects caused by solvent evaporation. Carbon materials, conductive agents, and binders are uniformly distributed and tightly compressed under high pressure to form dense, regularly structured electrodes. Compared with wet processes, dry electrodes increase compaction density by 5%–10% and support higher active material loading. Under the same volume footprint, cells can accommodate more active materials, boosting energy density by 15%–20%. This breakthrough effectively overcomes traditional performance limitations and meets the market demand for high-energy-density, long-cycle-life new energy batteries.
Solid-state batteries undergo continuous volume expansion and contraction during charging and discharging, placing high requirements on electrode structural stability. Traditional wet electrodes rely purely on physical adhesion after drying, resulting in weak bonding strength between active materials and current collectors. After long-term cycling, wet electrodes are prone to delamination, peeling, and powder shedding, which gradually increase internal resistance and accelerate capacity decay, failing to meet long-term stable operating standards.
Dry electrodes form a robust integrated structure through binder fibrillation interweaving and high-temperature thermal compression. Active materials, conductive networks, and current collectors are tightly bonded with significantly improved mechanical strength and structural toughness. This unique interwoven network structure effectively buffers volume deformation during cycling, preventing electrode cracking and conductive network disconnection. It greatly enhances cycling stability and service life, fully satisfying the demanding high-frequency and long-lifetime operating conditions of automotive power batteries and high-end industrial equipment.
Traditional wet production involves complicated procedures, including solvent preparation, coating, high-temperature drying, solvent recovery, and waste gas and liquid treatment. It requires large-scale production lines, extensive plant space, and high energy consumption. In addition, the procurement, recycling, and environmental treatment costs of NMP solvents remain high, keeping solid-state battery manufacturing expensive and hindering commercialization progress.
Dry electrode technology eliminates high-temperature baking, solvent addition, and VOC recovery procedures, greatly simplifying production workflows and shortening production lines. It significantly reduces equipment investment and site occupation. Practical production data shows that dry processes reduce energy consumption by more than 40% and cut overall manufacturing costs by 10%–20%. The solvent-free production model also eliminates solvent consumption and environmental treatment pressure, delivers higher production yield and lower maintenance costs, lowers the industrialization threshold, and provides solid cost support for large-scale commercial production of solid-state batteries.
Wet-processed electrodes inevitably retain trace residual solvents. Under high-temperature and high-pressure operating conditions, residual solvents continuously trigger side reactions, causing excessive self-discharge, cell swelling, and poor thermal stability, which pose potential safety risks. In addition, inconsistent residual solvent levels lead to large performance variations between individual cells, undermining the overall performance and service life of battery packs.
Dry electrodes feature a completely solvent-free, impurity-free internal electrochemical system, fundamentally eliminating solvent-induced side reactions and hidden safety hazards. Dry-processed cells deliver lower self-discharge, higher consistency, and minor performance fluctuation under extreme temperatures. They exhibit superior thermal runaway resistance and structural robustness, meeting the strict safety, stability, and reliability standards for automotive power systems, large-scale energy storage, and high-end industrial equipment, filling the safety gap restricting the commercialization of solid-state batteries.
Dry electrode technology is not merely a minor process upgrade but a disruptive manufacturing solution tailored for solid-state battery systems. It systematically solves the core pain points of traditional wet processes, including poor solid electrolyte compatibility, limited energy density, insufficient structural stability, high manufacturing costs, and latent safety risks. Balancing high performance, superior safety, low cost, and high producibility, dry electrode technology has become a key enabler for the transition of solid-state batteries from laboratory research to large-scale commercialization and represents the mainstream technological direction for future power and energy storage battery iteration.